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Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utilize its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive.[11] Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates.[11] Its dissolution in water is strongly exothermic. Concentrated aqueous solutions are sometimes called potassium lyes. Even at high temperatures, solid KOH does not dehydrate readily.[12] Structure At higher temperatures, solid KOH crystallizes in the NaCl crystal structure. The  OH− group is either rapidly or randomly disordered so that it is effectively a spherical anion of radius 1.53 Å (between Cl− and F− in size). At room temperature, the OH− groups are ordered and the environment about the K+ centers is distorted, with K+−OH− distances ranging from 2.69 to 3.15 Å, depending on the orientation of the OH group. KOH forms a series of crystalline hydrates, namely the monohydrate KOH · H2O, the dihydrate KOH · 2H2O and the tetrahydrate KOH · 4H2O.[13]
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